How is coffee decaffeniated

How Decaf Coffee Is Made: Methods, Pros and Cons

Cup of decaf coffee

Decaf has a reputation problem. Plenty of people assume it is flavorless, chemically treated or not really coffee at all. In reality, good decaf starts as the same green beans as regular coffee and goes through a careful process to wash the caffeine out before roasting. How that is done makes a real difference to the taste, and knowing the methods helps you find a decaf worth drinking.

How Is Decaf Coffee Made?

Decaf, defined

Decaf coffee is made by removing caffeine from green, unroasted coffee beans, usually with water, carbon dioxide or a solvent, before the beans are dried and roasted normally. In the US, decaf is expected to have at least 97 percent of its caffeine removed.

  1. Starts green: caffeine is always removed before roasting, never after.
  2. Water-soluble: caffeine dissolves in water, which is the key to every method.
  3. Not zero: a cup of decaf still has a small amount of caffeine.

The Decaf Process, Step by Step

1. Green beans

Raw, unroasted beans arrive from the farm.

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2. Soak or steam

Water or steam swells the beans and opens their pores.

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3. Extract caffeine

Water, CO2 or a solvent draws the caffeine out.

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4. Dry

Beans are dried back to normal moisture.

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5. Roast

Roasted like any coffee, usually with extra care.

The tricky part is step three: removing caffeine without stripping away the hundreds of other compounds that make coffee taste like coffee. Each method solves that problem differently. Decaf beans also come out of the process darker and more porous, so roasters handle them gently; our guide to roast levels explains why that matters for flavor.

Decaffeination Methods: Pros and Cons

Decaf coffee beans and a cup of decaffeinated coffee
Swiss Water Process
How it works
Water and carbon filters only; caffeine is filtered out of a flavor-rich water bath
Pros
Chemical-free, popular with organic and specialty roasters
Cons
Costs more; can soften bright acidity
CO2 Process
How it works
Pressurized carbon dioxide targets caffeine molecules
Pros
Very selective, keeps flavor well, no harsh solvents
Cons
Expensive equipment, mostly used for large lots
Sugarcane (Ethyl Acetate)
How it works
A solvent made from fermented sugarcane, common in Colombia
Pros
Naturally derived, adds a gentle sweetness
Cons
Some taste a faint fruity note
Methylene Chloride
How it works
A chemical solvent, applied directly to beans or to the water they soaked in
Pros
Cheap and effective; residues are tiny and regulated
Cons
Many drinkers prefer to avoid synthetic solvents

If the bag does not say how the coffee was decaffeinated, it was most likely a solvent method. Roasters using Swiss Water, CO2 or sugarcane processing almost always print it on the label, because it is a selling point.

How Much Caffeine Is in Decaf?

Regular brewed coffee, 8 ozabout 95 mg
Decaf brewed coffee, 8 ozabout 2 to 15 mg

Exact amounts vary by bean, method and brew strength. Several cups of decaf can add up to the caffeine in a small regular coffee.

For comparison across drinks, see our guide to how much caffeine is in a cup of coffee.

Pros and Cons of Drinking Decaf

Pro: coffee without the jitters

For people sensitive to caffeine, decaf avoids the racing heart, anxiety and stomach upset that regular coffee can bring.

Pro: an evening cup that will not keep you up

Decaf lets you enjoy coffee after dinner without disturbing sleep.

Pro: the ritual and the flavor

You keep the taste, aroma and routine of coffee, along with most of the other natural compounds in the bean.

Con: it is not caffeine-free

Trace caffeine remains, which matters if you must avoid it completely.

Con: flavor varies

Cheap decaf can taste flat or papery. Method, freshness and bean quality make a big difference.

Con: fewer choices

Most roasters offer only one or two decaf options, and they can cost more.

If you are cutting caffeine for medical reasons or during pregnancy, check with your doctor about how much is right for you; our guide to coffee during pregnancy covers the general guidance.

How to Choose a Good Decaf

Look for a named method, ideally Swiss Water, CO2 or sugarcane, and buy from a specialty roaster rather than a supermarket can. A roast date matters even more than usual, because decaf beans are more porous and go stale faster, so buy small bags and store them properly. Medium roasts usually taste best: light decaf can taste thin, and dark decaf can taste burnt. And as with any coffee, origin matters; a decaf from a good specialty coffee lot will taste far better than one made from leftovers.

Decaf Myths

“Decaf has no caffeine.” It has very little, but not none. “Decaf always tastes bad.” Older, cheaply processed decaf often did; modern specialty decaf can be genuinely excellent. “Decaf is full of chemicals.” Solvent residues are tiny and regulated, and chemical-free methods like Swiss Water are widely available. “Decaf is made from worse beans.” Sometimes it was, but many specialty roasters now decaffeinate the same high-quality coffees they sell regular.

Steve Keating
Written by
Steve Keating

Former roastery owner and coffee tour operator. Steve spent five years roasting coffee for his own shop and wholesale customers. More about Steve